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Jul 18, 2022 · Plastic waste triggers a series of concerns because of its disruptive impact on the environment and ecosystem. From the point of view of catalysis, however, end-of-life plastics can be seen as an untapped feedstock for the preparation of value-added products. Thus, the development of diversified catalytic approaches for plastics valorization is urgent. Previous reviews of this field have ... Dr. Buonsanti is an expert in catalysis and materials chemistry focusing on the design and use of nanomaterials to drive chemical, electrochemical, and …ACS Catalysis is a monthly peer-reviewed scientific journal established in 2011 by the American Chemical Society. The journal covers research on all aspects of heterogeneous, homogeneous, and biocatalysis. The editor-in-chief is Cathleen Crudden, who assumed the position in early 2021. Dec 2, 2022 · Artwork by chemistry graduate student, Alison Sy-min Chang, featured in ACS' DEIR Cover Art series. A group of STEM individuals with varying identities are working in tandem with one another to harvest the energy from the sun to develop a collective catalytic system that addresses the initial disassembly of the systemic blockades in STEM. In her editorial, she reflects on the influence that ... May 2, 2023 · Plasmonic catalysis is an ever-growing field in which chemical reactions are enabled by visible light excitation. The plasmonic effects provide a unique reaction environment, which can greatly affect chemical reaction processes. On the basis of extensive research on plasmon-induced chemical reactions, we focus on the fundamentals of plasmon-mediated catalytic selectivity and summarize recent ... Anionic ligands containing a nonbonded lone pair (i.e., amido, thiolate) are well-known to cooperate with a metal center in bifunctional catalytic reactions. An NHC CoII(κ3-SNS) imine–dithiolate complex (Co-3) effects the selective hydroboration of aldehydes (vs ketones) in 4–30 min at a 1 mol % loading in benzene (NHC = 2,5 …We have developed an efficient gold-catalyzed C–O cross-coupling reaction of (hetero)aryl iodides with primary and secondary alcohols via an AuI–AuIII catalytic ...Achieving high activity and selectivity of multicarbon products in the CO2 reduction reaction (CO2RR) on Cu-based electrocatalysts remains challenging due to the limited concentration of local OH–, sluggish CO2 diffusion, and competitive hydrogen evolution reaction. Herein, we report aerophilic nanocomposites of hydrophobic SiO2 …Professor Kazunari Domen has devoted his research career in catalysis to development of water splitting photocatalysts, mechanocatalytic water splitting, transition metal oxide mesoporous materials, transmission infrared spectroscopy, infrared reflection absorption spectroscopy (IRAS), time-resolved infrared laser spectroscopy, surface …Heteroatom doping can facilitate intrinsic activity via the tuning of electronic states. However, it is still rare to elucidate the role of a specific metal sulfide electronic state and simultaneously enhance the CO2 electroreduction reaction (CO2RR) stability. SnS is well-known for its ability to produce HCOOH; however, its long-term operational stability …Herein, we describe the design and development a new nickel pincer complex that catalyzes the direct coupling of primary alkyl halides with terminal alkynes at ...Taking 50 years of effort, ambient pressure X-ray photoelectron spectroscopy (APXPS) has become a useful characterization tool for studies in heterogeneous catalysis and electrocatalysis. This achievement is realized not by mere improvement of instrumentation but through interactions between the desire to explore new scientific …ACS Catalysis, ACS Central Science, ACS Chemical Biology, ACS Chemical Health ... Catalysts for Autothermal Cracking of n-Hexane.” ×. ✓ Watched. Now Playing. 0.An efficient method for the construction of 12-membered heterocycles with a trifluoromethyl group (3) was achieved via a nondecarboxylative Pd-catalyzed [6 + 6] annulation of six-membered trifluoromethyl benzo[d][1,3]oxazinones (1) with four-membered vinyl oxetanes (2). A variety of relatively large heterocycles 3 featuring a stereogenic …Seawater electrolysis is an attractive approach for producing clean hydrogen fuel in scenarios where freshwater is scarce and renewable electricity is abundant. However, chloride ions (Cl–) in seawater can accelerate electrode corrosion and participate in the undesirable chlorine evolution reaction (CER). This problem is especially acute in acidic …Low-temperature dry reforming of methane (DRM) can avoid the sintering of nickel and reduce the cost of the process. However, inefficient activation of CO2 and oxidization of Ni0 hamper the catalytic performance of Ni-based catalysts at low temperatures. Herein, a Ni/ZrO2 catalyst was prepared and used in the DRM reaction, …Heterogeneous catalysis is one of the pillars of chemical and energy industries. As research on this important topic advances, heterogeneous catalysis will be a central science in driving the transition to their eventual carbon neutral operation due to the ease of separation and reusability. ... ACS and Elsevier journals. Prof. Luque was named ...Seawater electrolysis is an attractive approach for producing clean hydrogen fuel in scenarios where freshwater is scarce and renewable electricity is abundant. However, chloride ions (Cl–) in seawater can accelerate electrode corrosion and participate in the undesirable chlorine evolution reaction (CER). This problem is especially acute in acidic …Rhenium-Catalyzed Dehydration and Deoxydehydration of Alcohols and Polyols: Opportunities for the Formation of Olefins from Biomass. Suresh Raju. , Marc-Etienne …Cu-oxide catalysts have a tendency to deactivate dramatically in reverse water gas shift (RWGS) reaction, because of the aggregation of supported copper particles at high temperatures. Herein, β-Mo2C, which is a typical type of transition-metal carbide, has been demonstrated to be capable of dispersing and stabilizing copper particles. Cu/β-Mo2C …Understanding how multicopper oxidases (MCOs) reduce oxygen in We report here selective reduction of CO to acetate usi When it comes to installing a new AC unit, many homeowners focus solely on the upfront cost of the equipment itself. However, there are several hidden costs associated with a new A... Here, we proposed a computation-driven s Development of heterogeneous catalysts for alcohol transformation into nitriles under oxidant-free conditions is a challenge. Considering the C–H activation on α-carbon of primary alcohols is the rate-determining step, decreasing the activation energy of C–H activation is critical in order to enhance the catalytic activity. Several NiM/Al2O3 … January 5, 2024 Vol. 14 Issue 1. pp. 1-593. Check out a complet

Covalent Attachment of Cobalt Bis (Benzylaminedithiolate) to Reduced Graphene Oxide as a Thin-Film Electrocatalyst for Hydrogen Production with Remarkable Dioxygen Tolerance. Virginia A. Larson. and. Nicolai …Nature Catalysis - Multiple ... van der Hoeven, J. E. S. et al. Entropic control of HD exchange rates over dilute Pd-in-Au alloy nanoparticle catalysts. ACS Catal. 11, …Selective oxidation of H2S to sulfur is an efficient process for industrial applications and environmental requirement to reduce the residual H2S in the Claus technology to an ultralow content (<0.1 ppm) before releasing the off-gas into the atmosphere. Recently, numerous research studies have been devoted to the development of highly active, selective and …ACS Catalysis is a monthly peer-reviewed scientific journal established in 2011 by the American Chemical Society. The journal covers research on all aspects of …The catalytic C–H silylation of sulfides with hydrosilanes is of much interest and importance but has remained unexplored to date. We report here the C–H silylation of methyl sulfides with hydrosilanes by an yttrium metallocene catalyst. The reaction took place regioselectively at the α-methyl C–H bond, affording the corresponding silylated sulfide …

Are you preparing for a job interview or an assessment that requires basic Microsoft Office skills? Look no further – we’ve got you covered. In this article, we will provide you wi...Mar 25, 2020 · We herein report the fabrication of a bifunctional iron nanocomposite catalyst, in which two catalytically active sites of Fe–Nx and Fe phosphate, as oxidation and Lewis acid sites, were simultaneously integrated into a hierarchical N,P-dual doped porous carbon. As a bifunctional catalyst, it exhibited high efficiency for direct oxidative cleavage of alkenes into ketones or their oxidation ... In this work, we develop a synthetic route to synthesize and integrate thin mesoporous silica nanowires into three-dimensional (3D) networks. Hierarchical pore ...…

Reader Q&A - also see RECOMMENDED ARTICLES & FAQs. Ketones are among the most useful functional groups in organic synthe. Possible cause: Metal hydrides (MHs) are featured for their reversible hydrogen absorption .